Solution to 8A has been deliberately left unsolved and is to be answered only by a non-regular/novice commenter, with proper annotation. Those who have answered earlier in the week, please give others a chance.
Open for anyone to solve, if not solved by 1 PM.
ACROSS
8 Fine hotel in spot alongside river (5) S?E?R ()
9 Features trains leaving France for capital of Turkey (9) QUALITIES QUALI(-f+t)TIES
11 Facing a very difficult situation, miner exits frantically (2,8) IN EXTREMIS*
12 Japanese seasoning picked up by mom is outstanding (4) MISO [T]
16 Relaxing with slim girl after drinking a bit of wine (7) THAWING {TH{A}{Wine}IN}{G}
17 Company reviewed suggestion to incorporate department making jam (7) OCCLUDE {CO<=}{CLU{D}E}
19 Copper and gold discovered at large Mexican city (7) CUAUTLA {CU}{AU}{AT+L}*
21 Hunter nearly snares sea-eagle (4) ERNE [T]
22 Arrives outside bar with ultimately glamorous beauty (10) COMELINESS {COME{LINE}S}{g...uS}
25 Prince left serious after bad attack (9) OFFENSIVE {pENSIVE}<=>{OFF}
27 Enters into a dispute with member wanting difficulty in puzzles (7,6) CROSSES SWORDS {CROSS{mESS}WORDS}
DOWN
4 Put out pastry to entertain queen (5) PIQUE {PI{QU}E}
5 One probing cartel is remarkably level-headed (9) REALISTIC {1} in {CARTEL+IS}*
6 Kill Mafia boss outside institute (2,2) DO IN {DO{I}N}
7 Model in retreat cuddling bisexual lady on island in capital city (7) TBILISI {SIT<=} over {BI}{L} on {I}
8 & 20 Be on the verge of breaking a law, like reckless yachtsman might do? (4,5,2,3,4) SAIL CLOSE TO THE WIND [DD]
10 They are seen in bars, straying on vacation, picking up attractive girls (4,7) SHOT GLASSES {St..nG} over {HOT}{LASSES}
13 Murderer outside pub reverses vehicle finally, runs over Chilean police officer (10) CARABINERO {CA{BAR<=}IN}{v...lE}{R}{O}
20 See 8 Down
24 Opening of academy by rising star (4) ANUS {A}{SUN<=}
Reference List
France = F, Maiden = M, Girl = G, Department = D, Large = L, Prince = P, Many = M, Member = M, English = E, Queen = QU, Bisexual = BI, Lady = L, Island = I, Runs = R, Over = O, Old = O

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